And where does "natural gas" come from?
That is sort of an interesting question.
On Earth, the assumption is that it comes from decaying biological matter that has been transported below and trapped below the surface by various geological processes, including silt layer buildup over swamps, plate tectonics, etc.
But, if there always was no life on Mars, then that could not account for what we see on Mars. The methane there would not be from photosynthesis of carbon dioxide and water.
Methane is also common in other planetary atmospheres where we don't think any life has ever existed. We think it forms in space and gets compacted into planets along with the other materials.
So, could some of the methane oozing out of the Earth be "primordial" instead of biological? Maybe. But, the geologic evidence is that most of it can be explained by biological processes.
The radioactive isotopes of hydrogen and carbon are too short lived to look for the "age" of very old methane. But, carbon has 2 stable isotopes, atomic weights 12 and 13. C-13 is rare on Earth. Somebody might try to used the ratio of C-13 to C-12 to distinguish different origins of some methane, but I have never heard of that.