Googllng a bit more, the Falcon 9 is rated for only 4,020 kg to Mars, which should be a roughly equivalent delta-V to an Orion reentry test mission.
The Falcon Heavy is rated for 16,800 kg payload to Mars. So, I would think that a Falcon Heavy could be used to test the Orion heat shield for a lunar return reentry - provided the staging works out for getting the second stage to the right altitude and then restarting and accelerating itself and the capsule back toward Earth at a final velocity of 25,000 mph (40,000 kph).
But, somebody would need to look at what stages need to fire for what periods of time to make that happen, to see if the current equipment could be easily configured to do that mission.
If the ESM had to be included to get the right flight parameters, that would be a problem, because that weighs 15,461 kg, and that plus a 9, 400 kg capsule would total 24,851 kg, which is more than the Falcon Heavy could seem to be able to handle for that mission.
Still, if the Falcon Heavy cansend 16,800 kg to Mars, I would think it could send the Orion capsule around the Moon, if necessary to get the proper reentry. The only hangup I see is whether the accuracy of the reentry parameters could be achieved without the service module attached to the capsule during the return. Maybe some sort of mission specific trans stage would be needed. And that could be expensive and time consuming to develop.