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CAMBRIDGE, Mass. -- Sulfur dioxide (SO2) may have played a key role in the climate and geochemistry of early Mars, geoscientists at Harvard University and the Massachusetts Institute of Technology suggest in the Dec. 21 issue of the journal Science. Their hypothesis may resolve longstanding questions about evidence that the climate of the Red Planet was once much warmer than it is today. <br /><br />The Science paper's authors are Itay Halevy, a Ph.D. candidate in Harvard's Department of Earth and Planetary Sciences; Daniel Schrag, professor of earth and planetary sciences and environmental engineering at Harvard; and Maria Zuber, professor of earth, atmospheric, and planetary sciences at MIT. <br /><br />"There is abundant evidence for a warmer climate, perhaps even a liquid water ocean, early in Martian history, between 3.5 and 4 billion years ago," says Schrag, the paper's senior author. "However, scientists have found it difficult to reconcile this evidence with our understanding of how the climate system is regulated on Earth." <br /><br />Over millions of years, the Earth's climate has been controlled by the carbon cycle and its effect on carbon dioxide, the main greenhouse gas. On Earth, there is a balance between carbon dioxide vented from volcanoes and chemical reactions with silicate rocks on the Earth's surface that remove carbon dioxide from the atmosphere and convert it to calcium carbonate, commonly known as limestone. Scientists believe that this balance has helped maintain Earth's habitability over the last 4 billion years. <br /><br />On Mars, there is not enough volcanic activity today to maintain this cycle. But this was not true some 4 billion years ago, when a giant volcanic complex called Tharsis erupted over tens to hundreds of millions of years -- and also a time when evidence suggests Mars had a much warmer climate. However, this carbon cycle on early Mars should have produced vast quantities of limestone like on Earth, and yet almost none has been