A few comments and questions:
1. The article states both
"The planet provides a brilliant target for the next generation of telescopes to probe its atmosphere, and for scientists to test the extreme limits of planetary habitability. 'Its luminosity and proximity make it an ideal candidate for future telescopes whose mission will be to observe the atmospheres of exoplanets directly,'"
and
"astronomers have not directly observed HD 20794d, nor taken a picture of it or even seen it in transit yet."
So, I am guessing that the editors just messed-up on the proper antecedent for "its luminosity" and are referring to the star, not the planet. A G6 star certainly gives more light to work with than the red dwarfs for which we have so many exoplanet sightings.
2. With a mass of 6.6 times that of the Earth, I would expect a much thicker atmosphere than any of the inner planets in our solar system. That might help stabilize its climate a lot, compared to Earth and Mars. And a water ocean plus "dry" land areas, particularly if they are glaciated so that ice survives more than 1 of that planet's years, would also help stabilize the climate.
3. The heat and climate in which life may have evolved could be under the ocean, in some sort of heat vent such as what we see on our midocean ridges. So even if the atmosphere freezes out and heats up to steaming conditions, some deep underwater habitats might be quite stable.
4. With a gravitational mass of 6.6 times Earth's, if its density is about the same as Earth's, then it would have an gravitational acceleration about twice Earth's on its surface. So, surface pressure would probably be substantially higher than Earth's, especially if it has a higher concentration of heavier gases, such as CO2, compared to O2 and N2 such as the situation on Venus. With a potentially thick and heavy atmosphere, water at the surface might not boil even in the heat of the planet's summer, although it would obviously evaporate faster when heated.
I hope I live long enough for those "next generation telescopes" to get some real data.