<font color="yellow">How is the bare ET prepped before the foam is applied? I'm sure it's cleaned but could the surface undergo some treatment to aid foam adhesion? Anodizing or etching for example. <br /><br />The documentary I remember watching seemed most concerned with void free application but there was little information about the state of the surface it was applied to. <br /><br />Could it be "roughened" with an etching treatment and would that help adhesion? <br /><br />Would a spray adhesive help? <br /><br />Could you "bag" the tank and treat it like one does when tent fumigating a house? <br /><br />Could you thermally bond a different foam formula to the bare tank surface much like baking enamel auto paint? And could a thermal treatment help bake-out voids? </font><br /><br /><i>Exactly</i><br /><br />I don't know the answers to your questions. I don't work at NASA. But these are all the right questions to ask. Surface preparation, priming agents, and proper curing environment are key to gaining excellent polymer adhesion to metal surfaces.<br /><br />Linear polyurethanes are made by the reaction of a di-isocyanate with a diol. The choice of the spacer group in the di-isocyonate and the diol greatly affects polymer properties such as rigidity, tear resistance, adhesion, Tg, foaming properties. In addition, triols can be used to creat branch points in the polymer network which can add much strength. Varying the di-isocyante/diol ratio has huge effects on polymer properties, since this affects the nature of the end group (which affects adhesion!) and the polymer chain lengths. So the materials ratio must be kept exactly right on both macroscopic and microscopic levels. Otherwise weak areas can be produced in the polymer.<br /><br />Finally, if the uncured di-isocyanate is exposed to water (humidity!!) during application or curing, a side reaction can occur with can produce and amine group and a molecule of CO2. If enough of this happens, this causes two <div class="Discussion_UserSignature"> <div class="Discussion_UserSignature" align="center"><em><font color="#0000ff">- - - - - - - - - - - - - - - - - - - - - -</font></em> </div><div class="Discussion_UserSignature" align="center"><font color="#0000ff"><em>I really, really, really miss the "first unread post" function.</em></font> </div> </div>