Jon: I agree CO2 can react with some minerals to form carbonates. But I don't think it will dissolve salts very well.<br /><br />Here are some solvent Hansen solubility parameters, for comparison:<br /><br /><b>molecule.......dispersion......polar.....H-bonding</b><br />liq CO2.................15.3.............6.9.........4.1<br />cyclohexanone.....16.8.............0............0.2<br />isopropanol..........15.8.............5.8.........16.4<br />H2O......................15.5.............16..........42.3 <br /><br />The solvency of liq CO2 varies a lot with applied pressure. Thus greasy compounds can be dissolved into liq CO2 at one pressure, then precipitated out at another pressure. Manipulating these differences in solubility with pressure is the subject of many patents on the industrial use of liq CO2 to separate and purify molecules.<br /><br />I don't know if liq CO2 at the right pressure could change in Hansen parameters enough to dissolve common ionic compounds. Possibly, I will have to check references when I get to work. <br /><br />As far as liq CO2 physically eroding and transporting minerals, I would expect it to be less effective than water. Why? Well in most erosion processes, water plays a chemical role in addition to physical (frictional) processes. Water does a great job in reacting with "fresh" surfaces and creates a layer of oxide or hydrated surface which prevents re-formation or re-deposition of a mineral. I just don't think CO2 would do this as well as water (yes CO2 could react to form carbonates in some cases). On the other hand, the low viscosity and surface tension of liq CO2 would let it penetrate better into fractures and crevices. But overall, I think water would erode most minerals faster.<br /><br />Jon, do you think there is any possibility of liq SO2, or liq H2S below the Martian surface (at high pressure)? These solvents, if they were present, would have some very interesting reactive and solubilizing properties. I know the rovers ha <div class="Discussion_UserSignature"> <div class="Discussion_UserSignature" align="center"><em><font color="#0000ff">- - - - - - - - - - - - - - - - - - - - - -</font></em> </div><div class="Discussion_UserSignature" align="center"><font color="#0000ff"><em>I really, really, really miss the "first unread post" function.</em></font> </div> </div>