The A-4 program didn't develop any new materials it "merely" (OK, that's a big merely!) refined mechanisms and techniques. The A-4 was made of aluminum alloy, steel, rubber, plywood--all materials available since the 20s. LOX was an easily available industrial material. Fire engines were already using turbines that could pump liquids at the speeds and volumes the A-4 needed. (von Braun approached a manufacturer of turbines with his "impossible" specs for the A-4's fuel pump and was told to go to the Berlin fire department--they had been using pumps with those flow rates for years.) The big breakthroughs were mainly conceptual--actively cooling the combustion chamber. Connecting a gyroscope to steering vanes in the exhaust flow to control the orientation, etc. Most all of which were patented by Goddard in the 20s. Also the a-4/V-2 was optimized as a weapon not a launch vehicle--von Braun was actually arrested by the SS because they thought he was more interested in space than war. <br /><br />I still say that all of the materials were in place by the end of WWI to build an unmanned rocket capable of reaching orbit, assuming a wealthy country like the US put as much effort into it as they did say building the Panama Canal. Even thought the A-4/V-2 was the state of the art in the 40s it was optimized as a weapon (a lot of effort went into making sure it came down more-or-less near its intended target rather than increasing its velocity or reducing its weight). And besides there were other technologies not pursued at the time that could have worked better for just putting a payload into orbit as opposed to winning a war. Hybrid rockets, the BIS's "cellular" solid rocket, a giant canon sunk in the ground in Florida <img src="/images/icons/wink.gif" /> but "Cavorite" completely out of the question!<br /><br />The German rocket program (or its equivalent) could easily have been started before 1933 if anyone with money really wanted to do it. It took the NAZIs and their desi