Way back...about 2 years prior Challenger, inspired after reading a supplier's junk mail advertisement on o-ring materials, I remember discussing with friends that the o-ring materials choice was not well thought through (Viton o-rings). At the time, I wondered why the engineers had not chosen Kalrez (very expensive!) or a silicone o-ring material because of their very superior thermal properties. And, since there have been several o-ring burnthroughs on different missons (old-tang design), I thought then (and still think!!) that the o-ring thermal decomposition temperature should be given very high consideration.<br /><br />data from an o-ring table I have:<br />o-ring material/ / brittle point / / decomposition temperature///% elongation 'til breakage//%compression set at 200C<br />EPDM // -40C//121C//200%//NA -decomposes<br />VITON //-13C//204C//125%//45%<br />Silicone //-90C//235C//?//?<br />Kalrez / / -45C / / 349C / /180%//30%<br /><br />chemical inertness:<br />EPDM - rather bad to greases<br />VITON - OK to some greases<br />Silicone - swells badly<br />Kalrez - absolutely inert in almost everything by HF<br /><br />Then I find this reference from 1992,
http://techreports.larc.nasa.gov/ltrs/PDF/tp3226.pdf in which the NASA researcher recommends a new grade of Viton o-ring for the upgraded SRB, good to -26C, which is apparently what we use today. The basic reason driving this choice is that the o-ring must be compatible with a calcium containing grease (page 4) used to seat the o-ring and to help prevent corrosion. Kalrez o-rings were never considered by this researcher.<br /><br />My opinion as a chemist is that this report is of rather limited research quality. What the researchers should have done is first to test the thermal elastic properties of the full range of o-ring materials available, using a gease compatible for each, and then make the o-ring decision. The grease used to seat t <div class="Discussion_UserSignature"> <div class="Discussion_UserSignature" align="center"><em><font color="#0000ff">- - - - - - - - - - - - - - - - - - - - - -</font></em> </div><div class="Discussion_UserSignature" align="center"><font color="#0000ff"><em>I really, really, really miss the "first unread post" function.</em></font> </div> </div>