<p><BR/>Replying to:<BR/><DIV CLASS='Discussion_PostQuote'>I must say that i cam coming round to the brine idea. But there is one big problem. The MECA wet chemistry indicated that salinity was very low, driniking water quality in fact. So there should not be any brines at these temperatures. Unless there is a very strong salinity gradient in the soil, which seems unlikely, as salinities are generally highest at the surface, due to evaporation.Jon <br />Posted by jonclarke</DIV></p><p>Jon,</p><p>Here's a thought, to account for the unusual behaviors observed so far with the attempts to scoop up the highly hydrated soil....I am speaking as a chemist and not a geologist, so I don't know if my very speculative hypothesis is possible in soil chemistry, or in ice/soil mixes. But I do know what can happen in reaction flasks.</p><p>What is the possibility that the ices/soils contain a buffered solution of silicic acid? Silicic acid polymerizes between pH 7-8, if I recall correctly, and especially as the water evaporates. And this was the pH measured for the soils. Polymerized silicic acid can be quite sticky to materials which have polar groups, and especially hydroxyl groups decorating their surfaces. Silicic acid polymers can thus cause soil particles in which the soil contains hydroxyl groups, or metal oxides, to adhere to each other and clump. And I suspect silicic acid polymers can adhere pretty well to metal surfaces, if those metal surfaces have a coating of oxide (since the top surface of any oxide coat in a hydrated environment contains pendant hydroxyl groups)...what is the surface of the scoop made of? </p><p>Silicic acid can also polymerize to form tiny nanoparticles and colloids in water, in the right conditions. These nanoparticles then gradually clump up to form larger masses. When they substantially dry, silicic acid polymers become white friable silicate powders.</p> <div class="Discussion_UserSignature"> <div class="Discussion_UserSignature" align="center"><em><font color="#0000ff">- - - - - - - - - - - - - - - - - - - - - -</font></em> </div><div class="Discussion_UserSignature" align="center"><font color="#0000ff"><em>I really, really, really miss the "first unread post" function.</em></font> </div> </div>